Capital structure theory explained by combination of capital sources are still rarely implemented in cooperatives enterprises especially in Indonesia, also cooperative financial managers have not been aware if this theory very importance. The purpose of this study is to investigate decision of cooperative capital structure and its impact on profitability and firm value. This research use statistical approach by using path analysis so that it can be known magnitude of direct and indirect impact between independent and dependent variables, this model is applied to test the panel treshold impact of cooperative capital structure on profitability and firm value from 2011 to 2015 with sample size 52 cooperative in West Java using the simple random sampling technique. In this study, cooperative capital structure described by Debt to Asset Ration (DAR), Profitability is described by Return on Equity (ROE) and Firm Value described by ratio of cooprative permanent capital or capital allowance plus grant to total equity. The results of this study, decision of cooperative capital structure has a significant impact on profitability, and cooperative capital structure and profitability have impact on firm value either directyly or indirectly, means capital structure theory also applicable on cooperative enterprises that have certain characteristics. Implication of this research, indicate that profitability and firm value can be improved by decision of cooperative capital structure through increasing debt capital sources, cooperative profitability and firm value can be leveraged by decision of capital structure.